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Highly selective and sensitive chemosensor based on 2,3-diaminophenazine hydrochloride for the detection of cyanide in pure water and its application in plant seed samples.

Authors :
Yong, Bi-Rong
Wei, Tai-Bao
Qu, Wen-Juan
Lin, Qi
Zhang, You-Ming
Yao, Hong
Source :
New Journal of Chemistry; 9/21/2018, Vol. 42 Issue 18, p14766-14771, 6p
Publication Year :
2018

Abstract

In this study, we prepared an efficient chemosensor based on 2,3-diaminophenazine hydrochloride, and it exhibited good dissolvability in water; more importantly, it could act as an efficient chemodosimeter for the selective detection of CN<superscript>−</superscript> in pure water. Upon reacting with CN<superscript>−</superscript>, 2,3-diaminophenazine hydrochloride (Q1) displayed a remarkable visible and fluorescence response simultaneously with significant changes in both absorption and fluorescence spectra. Furthermore, the absorption and fluorescence detection limits of CN<superscript>−</superscript> were 1.95 × 10<superscript>−7</superscript> M and 1.13 × 10<superscript>−9</superscript> M, respectively. For practical applications, test strips based on this chemosensor could serve as convenient CN<superscript>−</superscript> detection tools. The chemosensor was also successfully applied to the detection of CN<superscript>−</superscript> in plant seeds and several natural water samples. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
11440546
Volume :
42
Issue :
18
Database :
Complementary Index
Journal :
New Journal of Chemistry
Publication Type :
Academic Journal
Accession number :
131701733
Full Text :
https://doi.org/10.1039/c8nj02316f