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Highly selective and sensitive chemosensor based on 2,3-diaminophenazine hydrochloride for the detection of cyanide in pure water and its application in plant seed samples.
- Source :
- New Journal of Chemistry; 9/21/2018, Vol. 42 Issue 18, p14766-14771, 6p
- Publication Year :
- 2018
-
Abstract
- In this study, we prepared an efficient chemosensor based on 2,3-diaminophenazine hydrochloride, and it exhibited good dissolvability in water; more importantly, it could act as an efficient chemodosimeter for the selective detection of CN<superscript>−</superscript> in pure water. Upon reacting with CN<superscript>−</superscript>, 2,3-diaminophenazine hydrochloride (Q1) displayed a remarkable visible and fluorescence response simultaneously with significant changes in both absorption and fluorescence spectra. Furthermore, the absorption and fluorescence detection limits of CN<superscript>−</superscript> were 1.95 × 10<superscript>−7</superscript> M and 1.13 × 10<superscript>−9</superscript> M, respectively. For practical applications, test strips based on this chemosensor could serve as convenient CN<superscript>−</superscript> detection tools. The chemosensor was also successfully applied to the detection of CN<superscript>−</superscript> in plant seeds and several natural water samples. [ABSTRACT FROM AUTHOR]
- Subjects :
- CHEMORECEPTORS
CYANIDES
FLUORESCENCE spectroscopy
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 42
- Issue :
- 18
- Database :
- Complementary Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 131701733
- Full Text :
- https://doi.org/10.1039/c8nj02316f