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Recent advances in Ni−Al bimetallic catalysis for unreactive bond transformation.
- Source :
- SCIENCE CHINA Chemistry; Aug2018, Vol. 61 Issue 8, p1004-1013, 10p
- Publication Year :
- 2018
-
Abstract
- Ni−Al bimetallic catalysis proves to be an efficient catalytic strategy for unreactive bond transformations. Recently, chiral bifunctional ligands, especially amphoteric secondary phosphine oxide (SPO) ligand, are used for a more powerful synergistic effect in the bimetal-catalyzed reactions, providing not only milder reaction conditions and higher reactivity but also excellent reaction selectivity. Herein, we give a brief review on the development of Ni−Al bimetallic catalytic system and highlight recent advances in enantioselective Ni−Al bimetallic catalysis for unreactive bond transformation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16747291
- Volume :
- 61
- Issue :
- 8
- Database :
- Complementary Index
- Journal :
- SCIENCE CHINA Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 131207252
- Full Text :
- https://doi.org/10.1007/s11426-018-9333-x