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A multi-electron transfer ferrocene derivative positive redox moiety with improved solubility and potential.

Authors :
Xie, Congxin
Xu, Wenbin
Zhang, Huamin
Hu, Xiangping
Li, Xianfeng
Source :
Chemical Communications; 8/4/2018, Vol. 54 Issue 60, p8419-8422, 4p
Publication Year :
2018

Abstract

Rational molecular structure modification towards high performance redox couples attracts great concern. A ferrocene derivative N-(pyridin-2-ylmethylene)-1-(2-(diphenylphosphino) ferrocenyl) ethanamine (FeCp<subscript>2</subscript>PPh<subscript>2</subscript>RCN) with improved solubility and potential as well as multi-electron transfer behavior is designed and fabricated. Benefitting from the high operating current density and capacity of the battery, FeCp<subscript>2</subscript>PPh<subscript>2</subscript>RCN demonstrates promising prospects as a positive redox moiety. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
54
Issue :
60
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
130892587
Full Text :
https://doi.org/10.1039/c8cc04099k