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DBU-promoted Cu(OAc)2·H2O-catalysed coupling reactions of aryl iodides and sodium azide.
- Source :
- Journal of Chemical Research; Jun2018, Vol. 42 Issue 5, p247-250, 4p
- Publication Year :
- 2018
-
Abstract
- An efficient and simple protocol for the synthesis of aryl azides by the coupling of aryl iodides with sodium azide, in good to excellent yields in DMSO at 95 °C under catalysis by Cu(OAc)<subscript>2</subscript>·H<subscript>2</subscript>O and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), has been established. The optimised loadings of Cu(OAc)<subscript>2</subscript>·H<subscript>2</subscript>O and DBU were 10 mol% and 15 mol% respectively. [ABSTRACT FROM AUTHOR]
- Subjects :
- COPPER
ARYL halides
SODIUM azide
CATALYTIC activity
CRYSTAL structure
Subjects
Details
- Language :
- English
- ISSN :
- 17475198
- Volume :
- 42
- Issue :
- 5
- Database :
- Complementary Index
- Journal :
- Journal of Chemical Research
- Publication Type :
- Academic Journal
- Accession number :
- 130794608
- Full Text :
- https://doi.org/10.3184/174751918X15260507766192