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Solid‐State Electrolyte Anchored with a Carboxylated Azo Compound for All‐Solid‐State Lithium Batteries.
- Source :
- Angewandte Chemie International Edition; 7/9/2018, Vol. 57 Issue 28, p8567-8571, 5p
- Publication Year :
- 2018
-
Abstract
- Abstract: Organic electrode materials are promising for green and sustainable lithium‐ion batteries. However, the high solubility of organic materials in the liquid electrolyte results in the shuttle reaction and fast capacity decay. Herein, azo compounds are firstly applied in all‐solid‐state lithium batteries (ASSLB) to suppress the dissolution challenge. Due to the high compatibility of azobenzene (AB) based compounds to Li<subscript>3</subscript>PS<subscript>4</subscript> (LPS) solid electrolyte, the LPS solid electrolyte is used to prevent the dissolution and shuttle reaction of AB. To maintain the low interface resistance during the large volume change upon cycling, a carboxylate group is added into AB to provide 4‐(phenylazo) benzoic acid lithium salt (PBALS), which could bond with LPS solid electrolyte via the ionic bonding between oxygen in PBALS and lithium ion in LPS. The ionic bonding between the active material and solid electrolyte stabilizes the contact interface and enables the stable cycle life of PBALS in ASSLB. [ABSTRACT FROM AUTHOR]
- Subjects :
- LITHIUM cells
CARBOXYLATION
AZO compounds
SOLUBILITY
SUPERIONIC conductors
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 57
- Issue :
- 28
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 130525264
- Full Text :
- https://doi.org/10.1002/anie.201804068