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Anion–π interactions of highly π-acidic dipyridinium-naphthalene diimide salts.

Authors :
Tam, Teck Lip Dexter
Ng, Chee Koon
Lu, Xuefeng
Lim, Zheng Long
Wu, Jishan
Source :
Chemical Communications; 7/7/2018, Vol. 54 Issue 53, p7374-7377, 4p
Publication Year :
2018

Abstract

A highly π-acidic dipyridinium-naphthalene diimide acceptor shows anion–π interactions with halides and PF<subscript>6</subscript><superscript>−</superscript>. Lewis basicity and redox potential of the anion affect the chemistry, and photophysical and electrochemical properties, as well as both ionic and electrical conductivities. Our results provide insights into doping, degradation and ion transport mechanisms in organic n-type semiconductors. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
54
Issue :
53
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
130392150
Full Text :
https://doi.org/10.1039/c8cc03941k