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Ferromagnetic Behavior of an Uncommon Trinuclearcopper(II) Coordination Polymer Based on Tartarate and 1,2-bis(4-Pyridyl)ethane Linker.
- Source :
- Russian Journal of Coordination Chemistry; Jul2018, Vol. 44 Issue 7, p432-438, 7p
- Publication Year :
- 2018
-
Abstract
- A new Cu(II) based metal-organic framework (MOF) having formula [Cu<subscript>3</subscript>(H<subscript>2</subscript>Tar)(Tar)-(H<subscript>2</subscript>O)(Bpa)] · 3H<subscript>2</subscript>O (I) (H<subscript>4</subscript>Tar = tartaric acid, Bpa = 1,2-bis(4-pyridyl)ethane) has been characterized by elemental analysis, FT-IR spectra, thermal analysis, and single-crystal X-ray diffraction (CIF file CCDC no. 1575136). In I, the Cu(II) center are connected by four symmetry-related tartrate ligands into a 2D layer encapsulating trinuclear cluster, which are further bridged by Bpa molecules into a 3D framework. Complex I exhibits strong ferromagnetic behavior between metal centers. [ABSTRACT FROM AUTHOR]
- Subjects :
- COPPER
COORDINATION polymers
FERROMAGNETISM
ETHANES
TARTRATES
Subjects
Details
- Language :
- English
- ISSN :
- 10703284
- Volume :
- 44
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- Russian Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 130360807
- Full Text :
- https://doi.org/10.1134/S1070328418070072