Back to Search
Start Over
Dendrite‐Free and Performance‐Enhanced Lithium Metal Batteries through Optimizing Solvent Compositions and Adding Combinational Additives.
- Source :
- Advanced Energy Materials; 5/25/2018, Vol. 8 Issue 15, p1-1, 10p
- Publication Year :
- 2018
-
Abstract
- Abstract: The instability of lithium (Li) metal anodes due to dendritic growth and low Coulombic efficiency (CE) hinders the practical application of high‐energy‐density Li metal batteries. Here, the systematic studies of improving the stability of Li metal anodes and the electrochemical performance of Li metal batteries through the addition of combinational additives and the optimization of solvent compositions in dual‐salt/carbonate electrolytes are reported. A dendrite‐free and high CE of 98.1% for Li metal anode is achieved. The well‐protected Li metal anode and the excellent cyclability and rate capability of the 4‐V Li metal batteries are obtained. This is attributed to the formation of a robust, denser, more polymeric, and higher ionic conductive surface film on the Li metal anode via the electrochemical reductive decompositions of the electrolyte components and the ring‐opening polymerization of additives and cyclic carbonate solvents. The key findings of this work indicate that the optimization of solvent compositions and the manipulation of additives are facile and effective ways to enhance the performances of Li metal batteries. [ABSTRACT FROM AUTHOR]
- Subjects :
- LITHIUM cells
CHEMICAL decomposition
ELECTROLYTES
POLYMERIZATION
CARBONATES
Subjects
Details
- Language :
- English
- ISSN :
- 16146832
- Volume :
- 8
- Issue :
- 15
- Database :
- Complementary Index
- Journal :
- Advanced Energy Materials
- Publication Type :
- Academic Journal
- Accession number :
- 129954120
- Full Text :
- https://doi.org/10.1002/aenm.201703022