Back to Search
Start Over
A Ca(II) Coordination Polymer of 2-Carboxybenzaldehyde: Synthesis, Crystal Structure, and Catalytic Activity in Oxidation of Benzyl Alcohol.
- Source :
- Crystals (2073-4352); Apr2018, Vol. 8 Issue 4, p150, 1p
- Publication Year :
- 2018
-
Abstract
- The coordination polymers constructed by carboxylate ligand have shown novel structures and excellent properties. Therefore, a new Ca(II) coordination polymer with 2-carboxybenzaldehyde ligand, [Ca(L)<subscript>2</subscript>(H<subscript>2</subscript>O)<subscript>2</subscript>]<italic><subscript>n</subscript></italic> (L = 2-carboxybenzaldehyde), has been synthesized. Its structure has been identified by elemental analysis, FT-IR, and single-crystal X-ray diffraction technique. The Ca(II) coordination polymer exhibits a 1D chained structure by the bridging effect of carboxylate groups. The Ca(II) coordination polymer exhibited relatively good catalytic activity in the benzyl alcohol oxidation reaction with benzyl alcohol conversion (53.8%) and moderate benzaldehyde selectivity (83.3%). [ABSTRACT FROM AUTHOR]
- Subjects :
- COORDINATION polymers synthesis
BENZALDEHYDE analysis
CRYSTAL structure
Subjects
Details
- Language :
- English
- ISSN :
- 20734352
- Volume :
- 8
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Crystals (2073-4352)
- Publication Type :
- Academic Journal
- Accession number :
- 129774396
- Full Text :
- https://doi.org/10.3390/cryst8040150