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Structural phase diagrams and isomerism inflexible honeycomb-like 2D hydrogen bonded solid solutions.
- Source :
- CrystEngComm; 4/7/2018, Vol. 20 Issue 13, p1853-1861, 9p
- Publication Year :
- 2018
-
Abstract
- Solid solutions of hydrogen bonded networks of the formula ((1-2H<superscript>+</superscript>)<subscript>3x</subscript>(2-2H<superscript>+</superscript>)<subscript>3(1–x)</subscript>([Fe(CN)<subscript>6</subscript>]<subscript>2</subscript><superscript>3−</superscript>))·nH<subscript>2</subscript>O, where (1-2H<superscript>+</superscript>) and (2-2H<superscript>+</superscript>) are bisamidinium H bond donor entities, have been prepared and structurally analysed. The H bonded systems display a honeycomb-like structure, and depending on the x value, three different tilings of the (6,3) system are observed, leading to three different phases. The precise location of the H bond donor cations (2-2H<superscript>+</superscript>) has been determined, evidencing H bonding between adjacent cations. The thermal properties of the solid solutions have been studied. [ABSTRACT FROM AUTHOR]
- Subjects :
- HYDROGEN bonding
CHEMICAL reactions
THERMAL properties
Subjects
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 20
- Issue :
- 13
- Database :
- Complementary Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 128692011
- Full Text :
- https://doi.org/10.1039/c8ce00023a