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Synthesis of Subnanometer‐Sized Gold Clusters by a Simple Milling‐Mediated Solid Reduction Method.
- Source :
- Chinese Journal of Chemistry; Apr2018, Vol. 36 Issue 4, p329-332, 1p
- Publication Year :
- 2018
-
Abstract
- An effective solvent‐free method based on a solid‐reduction process was developed to fabricate ultrafine gold catalysts. By this method we revealed a strong size‐dependent activity of Au species in which subnanometer‐sized clusters exhibited the best activity in the hydrogenation of CO<subscript>2</subscript> to formate, with a turnover number of up to 9278 over 7 h at 90 °C. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1001604X
- Volume :
- 36
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Chinese Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 128483210
- Full Text :
- https://doi.org/10.1002/cjoc.201700750