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Design of bifunctional chiral phenanthroline ligand with Lewis basic site for palladium-catalyzed asymmetric allylic substitution.
- Source :
- Chemical Communications; 3/14/2018, Vol. 54 Issue 21, p2674-2677, 4p
- Publication Year :
- 2018
-
Abstract
- Conceptually new bifunctional chiral ligands were developed. The axially chiral N,N-bidentate phenanthroline ligand (S)-1 was found to be effective for Pd-catalyzed asymmetric allylic substitution of allyl acetate and dialkyl malonate. The intramolecular Lewis basic group from the hydroxybinaphthyl structure of (S)-1 played a pivotal role in the high reactivity and enantioselectivity. [ABSTRACT FROM AUTHOR]
- Subjects :
- PHENANTHROLINE
PALLADIUM catalysts
SUBSTITUTION reactions
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 54
- Issue :
- 21
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 128367066
- Full Text :
- https://doi.org/10.1039/c8cc00754c