Back to Search
Start Over
Controlled preparation of amphiphilic triblock-copolyether in a metal- and solvent-free approach for tailored structure-directing agents.
- Source :
- Chemical Communications; 3/4/2018, Vol. 54 Issue 18, p2220-2223, 4p
- Publication Year :
- 2018
-
Abstract
- Under mild conditions, PPO–PEO–PPO (“reverse Pluronics”) and PBO–PEO–PBO copolyether were generated by way of N-heterocyclic olefin-based organocatalysis. Reverse Pluronics with molar masses > 20 000 g mol<superscript>−1</superscript> could be synthesized with excellent control (Đ<subscript>M</subscript>≤ 1.03) and were converted into (ordered) mesoporous carbons via organic self-assembly to showcase the need for tailor-made copolymer as structure-directing agent. [ABSTRACT FROM AUTHOR]
- Subjects :
- AMPHIPHILES
ORGANOCATALYSIS
COPOLYMERS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 54
- Issue :
- 18
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 128220846
- Full Text :
- https://doi.org/10.1039/c7cc09031e