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A temperature-responsive C2 wagging vibration in Sc2C2@Cs-C82.
- Source :
- Chemical Communications; 1/21/2017, Vol. 54 Issue 7, p775-777, 3p
- Publication Year :
- 2018
-
Abstract
- The Raman spectra reveal molecular vibration information. Here we report a special temperature-dependent C<subscript>2</subscript> wagging vibration at 225 cm<superscript>−1</superscript> in Sc<subscript>2</subscript>C<subscript>2</subscript>@C<subscript>s</subscript>-C<subscript>82</subscript> by Raman spectroscopy and quantum-chemical calculations, which corresponds to the internal cluster motion in C<subscript>82</subscript>. This finding is of great importance in understanding the internal dynamics of metallofullerenes. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 54
- Issue :
- 7
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 127437738
- Full Text :
- https://doi.org/10.1039/c7cc08509e