Enhanced CE-QUAL-W2 model to predict the fate and transport of volatile organic compounds in water body: Gheshlagh reservoir as case study.

Intentional and/or accidental volatile organic compound (VOC) spill into water bodies may lead to severe contamination and health problems in water infrastructures. The importance and widespread use of petroleum products and the threats posed by these products on surface water resources in Iran necessitates the access to numerical hydrodynamic and water quality simulation models with appropriate capabilities. Simulation the fate and transport of VOC in both flowing and standing water bodies is a fairly complex problem. In this research, CE-QUAL-W2 model is modified to simulate the fate and transport of VOC [i.e., Methyl tert-butyl ether (MTBE), benzene] in standing and flowing water bodies. The performance of the modified CE-QUAL-W2 model is evaluated in a MTBE pollution spill at Khalife-Tarkhan river along the headwaters of Gheshlagh reservoir, Kordestan, Iran. The results show the modified CE-QUAL-W2 model's capability to depict the spatial and temporal variation of MTBE in comparison with recorded data from MTBE spill event of Gheshlagh reservoir. Based on the simulation results of modified CE-QUAL-W2 model, reservoir cleanup time in different meteorological and hydrological scenarios is evaluated. The results show Gheshlagh reservoir cleanup time reduced in scenarios that included air temperature reduction, wind speed increasing, and high inflow condition. [ABSTRACT FROM AUTHOR]