High-pressure metamorphic evolution of eclogite and associated metapelite from the Chuacús complex (Guatemala Suture Zone): Constraints from phase equilibria modelling coupled with Lu-Hf and U-Pb geochronology.

As is common in suture zones, widespread high-pressure rocks in the Caribbean region reached eclogite facies conditions close to ultrahigh-pressure metamorphism. Besides eclogite lenses, abundant metapelitic rocks in the Chuacús complex (Guatemala Suture Zone) also preserve evidence for high-pressure metamorphism. A comprehensive petrological and geochronological study was undertaken to constrain the tectonometamorphic evolution of eclogite and associated metapelite from this area in central Guatemala. The integration of field and petrological data allows the reconstruction of a previously unknown segment of the prograde P-T path and shows that these contrasting rock types share a common high-pressure evolution. An early stage of high-pressure/low-temperature metamorphism at 18-20 kbar and 530-580°C is indicated by garnet core compositions as well as the nature and composition of mineral inclusions in garnet, including kyanite-jadeite-paragonite in an eclogite, and chloritoid-paragonite-rutile in a pelitic schist. Peak high-pressure conditions are constrained at 23-25 kbar and 620-690°C by combining mineral assemblages, isopleth thermobarometry and Zr-in-rutile thermometry. A garnet/whole-rock Lu-Hf date of 101.8 ± 3.1 Ma in the kyanite-bearing eclogite indicates the timing of final garnet growth at eclogite facies conditions, while a Lu-Hf date of 95.5 ± 2.1 Ma in the pelitic schist reflects the average age of garnet growth spanning from an early eclogite facies evolution to a final amphibolite facies stage. Concordant U-Pb LA- ICP- MS zircon data from the pelitic schist, in contrast, yield a mean age of 74.0 ± 0.5 Ma, which is equivalent to a U-Pb monazite lower-intercept age of 73.6 ± 2.0 Ma in the same sample, and comparable within errors with a less precise U-Pb lower-intercept age of 80 ± 13 Ma obtained in post-eclogitic titanite from the kyanite-bearing eclogite. These U-Pb metamorphic ages are interpreted as dating an amphibolite facies overprint. Protolith U-Pb zircon ages of 167.1 ± 4.2 Ma and 424.6 ± 5.0 Ma from two eclogite samples reveal that mafic precursors in the Chuacús complex originated in multiple tectonotemporal settings from the Silurian to Jurassic. The integration of petrological and geochronological data suggests that subduction of the continental margin of the North American plate (Chuacús complex) beneath the Greater Antilles arc occurred during an Albian-Cenomanian pre-collisional stage, and that a subsequent Campanian collisional stage is probably responsible of the amphibolite facies overprint and late syncollisional exhumation. [ABSTRACT FROM AUTHOR]