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Invited article.
- Source :
- Molecular Physics; 1/10/2004, Vol. 102 Issue 1, p1-11, 11p
- Publication Year :
- 2004
-
Abstract
- Thermodynamic perturbation theory is used to calculate the free energies and resulting phase diagrams of binary systems of spherical colloidal particles and interacting polymer coils in a good solvent within an effective one-component representation of such mixtures, whereby the colloidal particles interact via a polymer-induced depletion potential. Monte Carlo simulations are used to test the convergence of the high temperature expansion of the free energy. The phase diagrams calculated for several polymer-to-colloid size ratios differ considerably from the results of similar calculations for mixtures of colloids and ideal (non-interacting) polymers, and are in good overall agreement with the results of an explicit two-component representation of the same system, which includes more than two-body depletion forces. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00268976
- Volume :
- 102
- Issue :
- 1
- Database :
- Complementary Index
- Journal :
- Molecular Physics
- Publication Type :
- Academic Journal
- Accession number :
- 12628533
- Full Text :
- https://doi.org/10.1080/0026897032000158315