Allowing the direct interaction of N-aryl α-diimines with a high valent metal chloride: one-pot WCl6-promoted formation of quinoxalinium salts.

Authors :: Bartalucci, Niccolò
Bortoluzzi, Marco
Funaioli, Tiziana
Marchetti, Fabio
Pampaloni, Guido
Zacchini, Stefano
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 10/14/2017, Vol. 46 Issue 38, p12780-12784, 5p
Publication Year :: 2017
Abstract: The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl<subscript>6</subscript> to react with N-(2,6-diisopropylphenyl) α-diimines, in CH<subscript>2</subscript>Cl<subscript>2</subscript> at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C–N coupling. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 14779226
Volume :: 46
Issue :: 38
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 125465176
Full Text :: https://doi.org/10.1039/c7dt03226a

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