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Allowing the direct interaction of N-aryl α-diimines with a high valent metal chloride: one-pot WCl6-promoted formation of quinoxalinium salts.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 10/14/2017, Vol. 46 Issue 38, p12780-12784, 5p
- Publication Year :
- 2017
-
Abstract
- The full potential of a high valent metal chloride as both a chlorinating and an oxidative agent was explored by allowing WCl<subscript>6</subscript> to react with N-(2,6-diisopropylphenyl) α-diimines, in CH<subscript>2</subscript>Cl<subscript>2</subscript> at room temperature. These α-diimines underwent unprecedented conversion to quinoxalinium cations via intramolecular C–N coupling. [ABSTRACT FROM AUTHOR]
- Subjects :
- IMINES
METAL chlorides
CATIONS
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 46
- Issue :
- 38
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 125465176
- Full Text :
- https://doi.org/10.1039/c7dt03226a