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Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step.
- Source :
- Chemistry - An Asian Journal; 8/17/2017, Vol. 12 Issue 16, p2048-2051, 4p
- Publication Year :
- 2017
-
Abstract
- In aqueous TiO<subscript>2</subscript> photocatalytic hydroxylation of weakly polar aromatics, a series of inverse H/D KIEs of 0.7-0.8 were observed, which is different than the normal H/D kinetic isotope effects (KIEs) usually observed for polar aromatics. This result indicated that the oxidation started by photo-induced h<subscript>vb</subscript><superscript>+</superscript> can be the rate-determining step. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 18614728
- Volume :
- 12
- Issue :
- 16
- Database :
- Complementary Index
- Journal :
- Chemistry - An Asian Journal
- Publication Type :
- Academic Journal
- Accession number :
- 124659746
- Full Text :
- https://doi.org/10.1002/asia.201700658