Back to Search
Start Over
Oxidation-induced C–H amination leads to a new avenue to build C–N bonds.
- Source :
- Chemical Communications; 8/18/2017, Vol. 53 Issue 64, p8984-8987, 4p
- Publication Year :
- 2017
-
Abstract
- In this work, we develop an oxidation-induced C–H functionalization strategy, which not only leads to a new avenue to build C–N bonds, but also leads to different site-selectivity compared with “classic directing-groups”. The high selectivity of our new catalytic system originates from the heterogeneous electron-density distribution of the radical cation species which are induced by single electron transfer between the aromatics and oxidant-Cu(ii) species. [ABSTRACT FROM AUTHOR]
- Subjects :
- AMINATION
ELECTRON density
CHARGE exchange
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 64
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 124534133
- Full Text :
- https://doi.org/10.1039/c7cc04955b