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Nickel sulfide nanospheres anchored on reduced graphene oxide in situ doped with sulfur as a high performance anode for sodium-ion batteries.
- Source :
- Journal of Materials Chemistry A; 5/21/2017, Vol. 5 Issue 19, p9322-9328, 7p
- Publication Year :
- 2017
-
Abstract
- NiS<subscript>x</subscript>–rGOS is prepared via a facile and cost effective hydrothermal process, with the structure of ultrafine NiS<subscript>x</subscript> nanospheres uniformly wrapped in the in situ S-doped rGO matrix. The uniform nanostructural NiS<subscript>x</subscript> and high conductivity of S-doped rGO (rGOS) can effectively increase the ionic and electronic conductivity of the NiS<subscript>x</subscript>–rGOS composite, thus resulting in high capacity utilization of the active materials. Moreover, the buffering layer provided by the rGOS matrix can accommodate the volume change of the NiS<subscript>x</subscript> and protect the nanoparticles from aggregation during the repeated cycling process. The as-prepared NiS<subscript>x</subscript>–rGOS composite demonstrates a high reversible capacity of 516 mA h g<superscript>−1</superscript> at 0.2 A g<superscript>−1</superscript> with a capacity retention of 96.8% over 100 cycles and a remarkable rate performance of 414 mA h g<superscript>−1</superscript> at 4 A g<superscript>−1</superscript>, possibly exhibiting the best electrochemical performances of nickel sulfide for sodium-ion batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 20507488
- Volume :
- 5
- Issue :
- 19
- Database :
- Complementary Index
- Journal :
- Journal of Materials Chemistry A
- Publication Type :
- Academic Journal
- Accession number :
- 123077182
- Full Text :
- https://doi.org/10.1039/c7ta02194a