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A Highly Active Manganese Catalyst for Enantioselective Ketone and Ester Hydrogenation.
- Source :
- Angewandte Chemie; 5/15/2017, Vol. 129 Issue 21, p5919-5922, 4p
- Publication Year :
- 2017
-
Abstract
- A new hydrogenation catalyst based on a manganese complex of a chiral P,N,N ligand has been found to be especially active for the hydrogenation of esters down to 0.1 mol % catalyst loading, and gives up to 97 % ee in the hydrogenation of pro-chiral deactivated ketones at 30-50 °C. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 129
- Issue :
- 21
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 122918673
- Full Text :
- https://doi.org/10.1002/ange.201702406