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A Highly Active Manganese Catalyst for Enantioselective Ketone and Ester Hydrogenation.
- Source :
- Angewandte Chemie International Edition; 5/15/2017, Vol. 56 Issue 21, p5825-5828, 4p
- Publication Year :
- 2017
-
Abstract
- A new hydrogenation catalyst based on a manganese complex of a chiral P,N,N ligand has been found to be especially active for the hydrogenation of esters down to 0.1 mol % catalyst loading, and gives up to 97 % ee in the hydrogenation of pro-chiral deactivated ketones at 30-50 °C. [ABSTRACT FROM AUTHOR]
- Subjects :
- MANGANESE catalysts
ENANTIOSELECTIVE catalysis
KETONES
ESTERS
HYDROGENATION
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 56
- Issue :
- 21
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 122917517
- Full Text :
- https://doi.org/10.1002/anie.201702406