Effect of titania addition on adhesion of silver colloids to glass substrate.

The purpose of this study was to investigate the effects of titania addition on adhesion strength of silver colloids to glass substrate. Our results indicated that when the pH was adjusted to 10, the mixed slurry of titania and silver colloids was stable with no sign of settling at approximately 4 hr. After film deposition by doctor blade method and subsequent sintering treatment, the adhesion strength between silver film and glass substrate was measured by both ASTM D3359 and D4541 standards. The results showed positive correlation of adhesion strength to both the titania concentration and sintering temperature. The adhesion strength reached 7.0 MPa when we added 8 wt% titania (based on silver) and sintered the film at 320°C for 20 min. X-ray photoelectron spectroscopy data revealed that interdiffusion of Ti into both glass substrate and silver colloid might be responsible for adhesion enhancement. On the other hand, the electrical resistivity of films increased with titania addition. This fact implied that we need to compromise between these two properties when titania addition was used to improve adhesion between silver colloid and glass substrate. An empirical model was subsequently proposed to simulate the compromise between adhesion strength and electrical resistivity. [ABSTRACT FROM PUBLISHER]