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Cationic AuIII versus AuI: Catalyst-Controlled Divergent Reactivity of Alkyne-Tethered Lactams.

Authors :
Alcaide, Benito
Almendros, Pedro
Cembellín, Sara
Fernández, Israel
Martínez del Campo, Teresa
Source :
Chemistry - A European Journal; 3/2/2017, Vol. 23 Issue 13, p3012-3015, 4p
Publication Year :
2017

Abstract

Switchable reactivity through cationic gold-based catalyst control built on the oxidation state, namely cationic Au<superscript>III</superscript> versus Au<superscript>I</superscript>, has been achieved in the direct functionalization of 2-azetidinone-tethered alkynyl indoles. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
23
Issue :
13
Database :
Complementary Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
121572270
Full Text :
https://doi.org/10.1002/chem.201700234