Back to Search
Start Over
A Facile Synthesis of N-Alkoxyacylimidoyl Halides from α-Nitro Ketones and Alkyl Halides in the Presence of NaHSO4/SiO2.
- Source :
- Synlett; 2017, Vol. 28 Issue 4, p489-493, 5p, 7 Diagrams, 2 Charts
- Publication Year :
- 2017
-
Abstract
- A novel method was developed for the synthesis of N-alkoxyacylimidoyl halide by the reaction of α-nitro ketone and alkyl halides in the presence of NaHSO<subscript>4</subscript>/SiO<subscript>2</subscript>. Nitrile oxides that are generated from α-nitro ketones by silica gel supported acid catalysts are the possible intermediate, which react with alkyl halides to form N-alkoxyacylimidoyl halides. Novel 17 N-alkoxyacylimidoyl halides were synthesized by this procedure. [ABSTRACT FROM AUTHOR]
- Subjects :
- HALIDES
NITRILE oxides
Subjects
Details
- Language :
- English
- ISSN :
- 09365214
- Volume :
- 28
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Synlett
- Publication Type :
- Academic Journal
- Accession number :
- 121374252
- Full Text :
- https://doi.org/10.1055/s-0036-1588914