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C8–H bond activation vs. C2–H bond activation: from naphthyl amines to lactams.
- Source :
- Chemical Communications; 11/21/2016, Vol. 52 Issue 90, p13307-13310, 4p
- Publication Year :
- 2016
-
Abstract
- Pd-catalyzed selective amine-oriented C8–H bond functionalization/N-dealkylative carbonylation of naphthyl amines has been achieved. The amine group from dealkylation is proposed to be the directing group for promoting this process. It represents a straightforward and easy method to access various biologically important benzo[cd]indol-2(1H)-one derivatives. [ABSTRACT FROM AUTHOR]
- Subjects :
- DEALKYLATION
CARBON-hydrogen bonds
LACTAMS
CHEMICAL synthesis
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 90
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 119248748
- Full Text :
- https://doi.org/10.1039/c6cc06358f