Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex.

Authors :: Wei, Rong-Jia
Nakahara, Ryohei
Cameron, Jamie M.
Newton, Graham N.
Shiga, Takuya
Sagayama, Hajime
Kumai, Reiji
Murakami, Youichi
Oshio, Hiroki
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 11/21/2016, Vol. 45 Issue 43, p17104-17107, 4p
Publication Year :: 2016
Abstract: A cyanide-bridged [Co<subscript>3</subscript>Fe<subscript>2</subscript>] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour. [ABSTRACT FROM AUTHOR]

Subjects :: CYANIDES
INTRAMOLECULAR charge transfer
SPIN crossover
TRIGONAL bipyramidal molecules
MOSSBAUER effect
SOLVATION

Language :: English
ISSN :: 14779226
Volume :: 45
Issue :: 43
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 119191474
Full Text :: https://doi.org/10.1039/c6dt03416k

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