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Cover Picture: Nanoconfinement Inside Molecular Metal Oxide Clusters: Dynamics and Modified Encapsulation Behavior (Chem. Eur. J. 40/2016).

Authors :
Wang, Zhe
Daemen, Luke L.
Cheng, Yongqiang
Mamontov, Eugene
Bonnesen, Peter V.
Hong, Kunlun
Ramirez‐Cuesta, Anibal J.
Yin, Panchao
Source :
Chemistry - A European Journal; 9/26/2016, Vol. 22 Issue 40, p14069-14069, 1p
Publication Year :
2016

Abstract

The nanoconfinement effect defined by the polyoxometalate nanocage renders the encapsulated bulky ligands rigid properties by significantly limiting and slowing down their diffusive motions. These ligands that partially cover the interfacial pore on the molybdenum oxide shells are able to block some large guest molecules from going inside the capsule cluster, which provides a convincing protocol for size‐selective encapsulation and separation. More information can be found in the Communication by P. Yin et al. on page 14131 ff. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
22
Issue :
40
Database :
Complementary Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
118172950
Full Text :
https://doi.org/10.1002/chem.201603744