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Oxidation of hydroquinones by a (salen)ruthenium(vi) nitrido complex.
- Source :
- Chemical Communications; 10/1/2016, Vol. 52 Issue 76, p11430-11433, 4p
- Publication Year :
- 2016
-
Abstract
- Hydroquinone is readily oxidized by a (salen)ruthenium(vi) nitrido complex in the presence of pyridine to give benzoquinone. Experimental and computational studies suggest that the reaction occurs via a novel mechanism that involves an initial electrophilic attack at the aromatic ring of the hydroquinone by the nitrido ligand. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 76
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 118125431
- Full Text :
- https://doi.org/10.1039/c6cc06231h