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Counter-anions-tuned crystal structure and intermolecular interactions of a series of iron (II) complexes derived from 4,4′-dimethyl-2,2′-bipyridine.
- Source :
- Molecular Crystals & Liquid Crystals; 2016, Vol. 631 Issue 1, p132-143, 12p
- Publication Year :
- 2016
-
Abstract
- A series of Fe(II) complexes with (ClO4)−(SeCN)−, (ClO4)−(SCN)−, (Fe2OCl6)2−, and 2(BF4)−counter-anions for complexes1–4, derived from dmbpy (4,4′-dimethyl-2,2′-bipyridine), were prepared. The single-crystal studies and the Hirshfeld surfaces analysis revealed that the (Fe2OCl6)2−anion results more distortional octahedral geometry of the cation than other anions. In particular, the (ClO4)−(SCN)−and (Fe2OCl6)2−anions lead to complexes2and3stabilized via C-H···π interactions and π···π interactions, which were not found in the other two complexes. However, the double-chain structure of complex4was formed by C-H···F and C-H···C hydrogen bonds interactions. Due to the influence of different anions, magnetic susceptibility measurements showed that complex1was in high-spin (HS) state and complex2was in low-spin (LS) state. [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 15421406
- Volume :
- 631
- Issue :
- 1
- Database :
- Complementary Index
- Journal :
- Molecular Crystals & Liquid Crystals
- Publication Type :
- Academic Journal
- Accession number :
- 117420839
- Full Text :
- https://doi.org/10.1080/15421406.2016.1149026