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A lanthanide complex for metal encapsulations and anion exchanges.
- Source :
- Chemical Communications; 8/25/2016, Vol. 52 Issue 66, p10125-10128, 4p
- Publication Year :
- 2016
-
Abstract
- A cationic lanthanide metalloligand with 3 dangling carboxylate groups on its periphery co-assembles with nitrate into a porous thermochromic solid responsive to both external cations and anions, owing to the presence of exchangeable NO<subscript>3</subscript><superscript>−</superscript> as well as cation cavities arising from cooperative orientation of free carboxylate groups. An especially interesting feature is the structural memory effect during crystallization exhibited by the metalloligand, even after dissolution and binding to secondary cations (Cu<superscript>2+</superscript>, Cd<superscript>2+</superscript>…). Moreover, the porous solid can undergo ion-exchange with various anions, leading to tunable thermochromic temperature and color range. [ABSTRACT FROM AUTHOR]
- Subjects :
- ION exchange resins
RARE earth metals
CARBOXYLATES
CRYSTALLIZATION
ANIONS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 66
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 117332706
- Full Text :
- https://doi.org/10.1039/c6cc05404h