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Influence of nucleobase stoichiometry on the self-assembly of ABC triblock copolymers.
- Source :
- Chemical Communications; 6/18/2016, Vol. 52 Issue 48, p7564-7567, 4p
- Publication Year :
- 2016
-
Abstract
- ABC triblock copolymers bearing adenine- and thymine-functionalized external blocks self-assembled into long-range, ordered lamellar microphase-separated morphologies on non-patterned substrates. Intermolecular hydrogen bonding formed thymine–adenine triplets and promoted self-assembly into well-defined lamellae consisting of poly(n-butyl acrylate) soft domains and complementary nucleobase hard domains, while thymine–adenine duplets contributed to superior mechanical properties. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 48
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 115938204
- Full Text :
- https://doi.org/10.1039/c6cc03502g