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A switchable dual organocatalytic system and the enantioselective total synthesis of the quadrane sesquiterpene suberosanone.

Authors :
Ren, Yajun
Presset, Marc
Godemert, Jeremy
Vanthuyne, Nicolas
Rodriguez, Jean
Coquerel, Yoann
Naubron, Jean-Valère
Giorgi, Michel
Source :
Chemical Communications; 5/14/2016, Vol. 52 Issue 39, p6565-6568, 4p
Publication Year :
2016

Abstract

The combination of aminocatalysis with N-heterocyclic carbene catalysis has been extended to a switchable dual catalytic system, which allowed a direct enantioselective entry to bridged bicyclo[3.n.1] ring systems and the total synthesis of the natural product (1R)-suberosanone. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
52
Issue :
39
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
115165835
Full Text :
https://doi.org/10.1039/c6cc01689h