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Addition of alkynes to digermynes: experimental insight into the reaction pathway.

Authors :
Tashkandi, Nada Y.
Pavelka, Laura C.
Caputo, Christine A.
Boyle, Paul D.
Power, Philip P.
Baines, Kim M.
Source :
Dalton Transactions: An International Journal of Inorganic Chemistry; 5/7/2016, Vol. 45 Issue 17, p7226-7230, 5p
Publication Year :
2016

Abstract

The addition of an alkynyl cyclopropyl mechanistic probe to a digermyne did not lead to any ring-opened rearrangement products indicating that the reaction pathway does not involve any vinylic radicals or cations and providing experimental insight into the addition of alkynes to digermynes. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14779226
Volume :
45
Issue :
17
Database :
Complementary Index
Journal :
Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
114825982
Full Text :
https://doi.org/10.1039/c6dt01015f