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Highly Stable Operation of Lithium Metal Batteries Enabled by the Formation of a Transient High-Concentration Electrolyte Layer.
- Source :
- Advanced Energy Materials; Apr2016, Vol. 6 Issue 8, pn/a-N.PAG, 10p
- Publication Year :
- 2016
-
Abstract
- Lithium (Li) metal has been extensively investigated as an anode for rechargeable battery applications due to its ultrahigh theoretical specific capacity and the lowest redox potential. However, significant challenges including dendrite growth and low Coulombic efficiency are still hindering the practical applications of rechargeable Li metal batteries. It is demonstrated that long-term cycling of Li metal batteries can be realized by the formation of a transient high-concentration electrolyte layer near the surface of Li metal anode during high rate discharge process. The highly concentrated Li<superscript>+</superscript> ions in this transient layer will immediately be solvated by the available solvent molecules and facilitate the formation of a stable and flexible solid electrolyte interphase (SEI) layer composed of a poly(ethylene carbonate) framework integrated with other organic/inorganic lithium salts. This SEI layer largely suppresses the corrosion of Li metal anode attacked by free organic solvents and enables the long-term operation of Li metal batteries. The fundamental findings in this work provide a new direction for the development of Li metal batteries that could be operated at high current densities for a wide range of applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16146832
- Volume :
- 6
- Issue :
- 8
- Database :
- Complementary Index
- Journal :
- Advanced Energy Materials
- Publication Type :
- Academic Journal
- Accession number :
- 114639848
- Full Text :
- https://doi.org/10.1002/aenm.201502151