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Dehydrogenative coupling of silanes with alcohols catalyzed by Cu3(BTC)2.
- Source :
- Chemical Communications; 2/14/2016, Vol. 52 Issue 13, p2725-2728, 4p
- Publication Year :
- 2016
-
Abstract
- Cu<subscript>3</subscript>(BTC)<subscript>2</subscript> is an efficient and reusable heterogeneous catalyst for the dehydrogenative coupling of silanes with alcohols. Activity data and CO adsorption suggest that Cu(ii) and in situ generated Cu(i) are the active species. Other MOFs such as Fe(BTC), MIL-101(Cr) and UiO-66(Zr) are unable to promote this cross-coupling. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 13
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 112761064
- Full Text :
- https://doi.org/10.1039/c5cc10216b