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Synergistic Interaction within Bifunctional Ruthenium Nanoparticle/ SILP Catalysts for the Selective Hydrodeoxygenation of Phenols.

Authors :
Luska, Kylie L.
Migowski, Pedro
El Sayed, Sami
Leitner, Walter
Source :
Angewandte Chemie; 12/21/2015, Vol. 127 Issue 52, p15976-15981, 6p, 1 Diagram, 3 Charts, 1 Graph
Publication Year :
2015

Abstract

Ruthenium nanoparticles immobilized on acid-functionalized supported ionic liquid phases (Ru NPs@SILPs) act as efficient bifunctional catalysts in the hydrodeoxygenation of phenolic substrates under batch and continuous flow conditions. A synergistic interaction between the metal sites and acid groups within the bifunctional catalyst leads to enhanced catalytic activities for the overall transformation as compared to the individual steps catalyzed by the separate catalytic functionalities. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00448249
Volume :
127
Issue :
52
Database :
Complementary Index
Journal :
Angewandte Chemie
Publication Type :
Academic Journal
Accession number :
112017104
Full Text :
https://doi.org/10.1002/ange.201508513