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FTIR spectroscopy of D2O and HDO molecules in the c-axis channels of synthetic beryl.

Authors :
MASHKOVTSEV, RUDOLF I.
THOMAS, VIKTOR G.
FURSENKO, DMITRY A.
ZHUKOVA, ELENA S.
USKOV, VLADIMIR V.
GORSHUNOV, BORIS P.
Source :
American Mineralogist; Jan2016, Vol. 101 Issue 1, p175-180, 6p, 2 Charts, 3 Graphs
Publication Year :
2016

Abstract

This paper presents the results of Fourier transform infrared (FTIR) spectroscopy of a synthetic beryl, containing D<subscript>2</subscript>O molecules in its c-axis channels, which we synthesized under hydrothermal conditions at 600 °C and 1.5 kbar. The frequencies of absorbance bands in the range of the stretching vibrations and their overtones and combination modes for D<subscript>2</subscript>O and HDO molecules have been assigned for the first time. On the basis of our assignments, the absorbance bands observed for the natural beryl in the range of the OD stretching vibrations have been explained. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
0003004X
Volume :
101
Issue :
1
Database :
Complementary Index
Journal :
American Mineralogist
Publication Type :
Academic Journal
Accession number :
112016677
Full Text :
https://doi.org/10.2138/am-2016-5432