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Synthesis, Crystal and Electronic Structures of the Pnictides AE3TrPn3 (AE = Sr, Ba; Tr = Al, Ga; Pn = P, As).
- Source :
- Crystals (2073-4352); 2015, Vol. 5 Issue 4, p433-446, 14p
- Publication Year :
- 2015
-
Abstract
- The new ternary arsenides AE<subscript>3</subscript>TrAs<subscript>3</subscript> (AE = Sr, Ba; Tr = Al, Ga) and their phosphide analogs Sr<subscript>3</subscript>GaP<subscript>3</subscript> and Ba<subscript>3</subscript>AlP<subscript>3</subscript> have been prepared by reactions of the respective elements at high temperatures. Single-crystal X-ray diffraction studies reveal that Sr<subscript>3</subscript>AlAs<subscript>3</subscript> and Ba<subscript>3</subscript>AlAs<subscript>3</subscript> adopt the Ba<subscript>3</subscript>AlSb<subscript>3</subscript>-type structure (Pearson symbol oC56, space group Cmce, Z = 8). This structure is also realized for Sr<subscript>3</subscript>GaP<subscript>3</subscript> and Ba<subscript>3</subscript>AlP<subscript>3</subscript>. The compounds Sr<subscript>3</subscript>GaAs<subscript>3</subscript> and Ba<subscript>3</subscript>GaAs<subscript>3</subscript> crystallize with the Ba<subscript>3</subscript>GaSb<subscript>3</subscript>-type structure (Pearson symbol oP56, space group Pnma, Z = 8). Both structures are made up of isolated pairs of edge-shared ALPN4 and GaPn4 tetrahedra (Pn = pnictogen, i.e., P or As), separated by the alkaline-earth Sr<superscript>2+</superscript> and Ba<superscript>2+</superscript> cations. In both cases, there are no homoatomic bonds, hence, regardless of the slightly different atomic arrangements, both structures can be rationalized as valence-precise [AE<superscript>2+</superscript>]<subscript>3</subscript>[TR<superscript>3+</superscript>][Pn<superscript>3-</superscript>]<subscript>3</subscript>, or rather [AE<superscript>2+</superscript>]<subscript>6</subscript>[Tr<superscript>2+</superscript>]Tr<subscript>2</subscript>Pn<subscript>6</subscript>]<superscript>12-</superscript>, i.e., as Zintl phases. [ABSTRACT FROM AUTHOR]
- Subjects :
- ELECTRONIC structure
CRYSTAL structure
ARSENIDES
Subjects
Details
- Language :
- English
- ISSN :
- 20734352
- Volume :
- 5
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Crystals (2073-4352)
- Publication Type :
- Academic Journal
- Accession number :
- 111971831
- Full Text :
- https://doi.org/10.3390/cryst5040433