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Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br.
- Source :
- Chemical Communications; 1/7/2016, Vol. 52 Issue 2, p308-311, 4p
- Publication Year :
- 2016
-
Abstract
- The Z and E isomers of the iodinated TTF derivative (Z,E)-Me<subscript>2</subscript>I<subscript>2</subscript>-TTF co-crystallize in a mixed-valence salt with Br<superscript>−</superscript> anions, and are segregated into Z and E stacks, each of them with a different charge localization pattern, which also revealed charge-assisted halogen bonding. [ABSTRACT FROM AUTHOR]
- Subjects :
- STATISTICAL correlation
MOLECULAR symmetries
ISOMERIZATION
HALOGENS
CHEMICAL bonds
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 111802294
- Full Text :
- https://doi.org/10.1039/c5cc08176a