Synthesis and physico-chemical properties of 2,7,12,17-tetraphenylporphycene and its metal complexes.

Authors :: Berezin, D.
Talanova, A.
Shukhto, O.
Guseinov, S.
Krest'yaninov, M.
Petrova, D.
Semeikin, A.
Source :: Russian Journal of General Chemistry; Aug2015, Vol. 85 Issue 8, p1876-1884, 9p, 4 Charts, 4 Graphs
Publication Year :: 2015
Abstract: Porphycene, β-phenyl-substituted analog of tetraphenylporphyrin, and its complexes with Cu(II) and Zn(II) have been prepared. Spectral parameters of the porphycene, its acid-base properties and thermal stability in the solid phase as well as its complexes stability towards dissociation in acidic medium have been studied by means of electronic absorption and NMR spectrometry, mass spectroscopy, thermogravimetry, and quantum chemistry simulation. [ABSTRACT FROM AUTHOR]

Subjects :: METAL complexes
COPPER compounds
ZINC compounds
CHEMICAL synthesis
CHEMICAL research

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