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One-dimensional porous Ag/AgBr/TiO2 nanofibres with enhanced visible light photocatalytic activity.
- Source :
- Chemical Papers; Nov2015, Vol. 69 Issue 11, p1411-1420, 10p
- Publication Year :
- 2015
-
Abstract
- One-dimensional (1D) Ag/AgBr/TiO<subscript>2</subscript> nanofibres (NFs) have been successfully fabricated by the one-pot electrospinning method. In comparison with bare TiO<subscript>2</subscript> NFs and Ag/AgBr/PVP (polyvinylpyrrolidone) NFs, the 1D Ag/AgBr/TiO<subscript>2</subscript> NFs photocatalyst exhibits much higher photocatalytic activity in the degradation of a commonly used dye, methylene blue (MB), under visible light. The photocatalytic removal efficiency of MB over Ag/AgBr/TiO<subscript>2</subscript> NFs achieves almost 100 % in 20 min. The photocatalytic reaction follows the first-order kinetics and the rate constant (k) for the degradation of MB by Ag/AgBr/TiO<subscript>2</subscript> NFs is 5.2 times and 6.6 times that of Ag/AgBr/PVP NFs and TiO<subscript>2</subscript> NFs, respectively. The enhanced photocatalytic activity is ascribed to the stronger visible light absorption, more effective separation of photogenerated electron-hole pairs, and faster charge transfer in the long nanofibrous structure. The Ag/AgBr/TiO<subscript>2</subscript> NFs maintain a highly stable photocatalytic activity due to its good structural stability and the self-stability system of Ag/AgBr. The mechanisms for photocatalysis associated with Ag/AgBr/TiO<subscript>2</subscript> NFs are proposed. The degradation of MB in the presence of scavengers reveals that h<superscript>+</superscript> and <superscript>•</superscript>O<superscript>−</superscript><subscript> 2</subscript> significantly contribute to the degradation of MB. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03666352
- Volume :
- 69
- Issue :
- 11
- Database :
- Complementary Index
- Journal :
- Chemical Papers
- Publication Type :
- Academic Journal
- Accession number :
- 109304566
- Full Text :
- https://doi.org/10.1515/chempap-2015-0151