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Aromatic Nitro Groups and Their Reactions with Chelated Ester Enolates.
- Source :
- Synthesis; 2006, Vol. 2006 Issue 19, p3341-3347, 7p
- Publication Year :
- 2006
-
Abstract
- Chelated amino acid ester enolates react with aromatic nitro compounds in a 1,3-addition mode at the nitro group giving amino acids bearing an aryl(hydroxy)amino side chain. Best results were obtained with trifluoroacetyl-protected glycinates. Two equivalents of enolate are necessary for complete conversion, because one equivalent is oxidized during the reaction. [ABSTRACT FROM AUTHOR]
- Subjects :
- GROUP 15 elements
AROMATIC compounds
ENOLATES
CHEMICAL reactions
AMINO acids
Subjects
Details
- Language :
- English
- ISSN :
- 00397881
- Volume :
- 2006
- Issue :
- 19
- Database :
- Complementary Index
- Journal :
- Synthesis
- Publication Type :
- Academic Journal
- Accession number :
- 103536189
- Full Text :
- https://doi.org/10.1055/s-2006-950228