Reassessment of MIPAS age of air trends and variability.

A new and improved setup of the SF₆ retrieval together with a newly calibrated version of MIPAS-ENVISAT level 1b spectra (version 5, ESA data version 5.02/5.06) was used to obtain a new global SF₆-data set, covering the total observational period of MIPAS from July 2002 to April 2012 for the first time. Monthly and zonally averaged SF₆-profiles were converted into mean age of air using a tropospheric SF₆-reference curve. The obtained data set of age of air was compared to airborne and balloonborne age of air measurements. The temporal evolution of mean age of air was then investigated in 10° latitude and 1-2km altitude bins. A regression model consisting of a constant and a linear trend term, 2 proxies for the quasi-biennial oscillation variation, sinusoidal terms for the seasonal and semi-annual variation and overtones was fitted to the age of air time series. The annual cycle for particular regions in the stratosphere was investigated and compared to other studies. The age of air trend over the total MIPAS-period consisting of the linear term was assessed and compared to previous findings of Stiller et al. (2012). While the linear increase of mean age is confirmed to be positive for the Northern mid-latitudes and Southern polar middle stratosphere, differences are found in the Northern polar upper stratosphere, where the mean age is now found to increase as well. The magnitude of trends in the Northern mid-latitude middle stratosphere is slightly lower compared to the previous version and the trends fit remarkably well to the trend derived by Engel et al. (2009). Negative age of air trends found by Stiller et al. (2012) are confirmed for the lowermost tropical stratosphere and lowermost Southern mid-latitudinal stratosphere. Differences to the previous data versions occur in the middle tropical stratosphere around 25 km, where the trends are now negative. Overall, the new latitude--altitude distribution of trends appears to be less patchy and more coherent than the previous one. The new data provide evidence of an accelerating shallow branch of the Brewer-Dobson circulation, at least in the Southern Hemisphere. Finally the age of air decadal trends are compared to trends calculated with simulated SF₆ values by the Karlsruhe Simulation Model of the Middle Atmosphere (KASIMA) and good agreement is found. The hemispheric asymmetry in the trends found in the MIPAS data are also indicated in the trends calculated with simulated SF₆ values by the KASIMA model. [ABSTRACT FROM AUTHOR]