Stable Cycling of Fe2O3 Nanorice as an Anode through Electrochemical Porousness and the Solid-Electrolyte Interphase Thermolysis Approach.

A new thread for improving the cycling stability of Fe₂O₃ nanorice is proposed through combining the electrochemical porousness (EP) effect and solid-electrolyte interphase (SEI) thermolysis approach. Starting from solid Fe₂O₃ nanorice, this process could be applied to prepare porous Fe₂O₃ nanorice with a good coating of a porous SEI thermolysis layer composed of carbon and Li₂O. The interconnecting pores and full coating of the SEI thermolysis layer provides not only mechanical resistance of the Fe₂O₃ nanorice against pulverization, but also high electrical and ionic conductivity over the electrode throughout long cell cycles. This method results in the enhancement of cycling ability and capacity, which is demonstrated by comparison with the starting Fe₂O₃ nanorice. After the EP and SEI thermolysis approach, the Fe₂O₃ nanorice exhibits an energy capacity retention about of 680 mAhg^-1 at a current density of 1000 mAg^-1 over 250 cycles, which is more than 82% of the initial reversible capacity. Moreover, it also has an excellent rate capability and high coulombic efficiency. This strategy provides a simple and convenient route toward stable charge/discharge cycling for not only Fe₂O₃, but also for other electrode materials that are subject to large volume changes and low charge voltages. At the same time, it also contributes to a fundamental understanding of improved cycling stability and reversible capacity for electrode materials. [ABSTRACT FROM AUTHOR]