Intramolecular N-coordination in ketiminoboranes.

Authors :: Bacon, Catherine E.
Mansour, Liz
Hayward, John J.
Rawson, Jeremy M.
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 3/28/2015, Vol. 44 Issue 12, p5284-5287, 4p
Publication Year :: 2015
Abstract: Treatment of the imine PhC(=NSiMe<subscript>3</subscript>)py with Et<subscript>2</subscript>BOMe or BF<subscript>3</subscript>·Et<subscript>2</subscript>O afforded bicyclic ketiminoboranes 4a and 4bvia intramolecular N-coordination. The basicity of the imine N is evidenced by their reactivity towards Brønsted and Lewis acids and the structures of 4a·HCl and 4b·BF<subscript>3</subscript> are reported as well as the dipyridyl imine derivative 4c·HCl. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 14779226
Volume :: 44
Issue :: 12
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 101531809
Full Text :: https://doi.org/10.1039/c5dt00196j