Back to Search
Start Over
Dynamics of a caged imidazolium cation–toward understanding the order-disorder phase transition and the switchable dielectric constant.
- Source :
- Chemical Communications; 2015, Vol. 51 Issue 22, p4568-4571, 4p
- Publication Year :
- 2015
-
Abstract
- A molecular compass-like behaviour is found in a perovskite-type cage compound (HIm)<subscript>2</subscript>[KCo(CN)<subscript>6</subscript>] (HIm = imidazolium cation). The dynamic changes in the HIm cation from the static to rotating state along with the rearrangement of the host cage result in switchable and anisotropic dielectric constants. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 51
- Issue :
- 22
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 101374233
- Full Text :
- https://doi.org/10.1039/c4cc08693g