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Modelling complex organic molecules in dense regions: Eley–Rideal and complex induced reaction.

Authors :
Ruaud, M.
Loison, J. C.
Hickson, K. M.
Gratier, P.
Hersant, F.
Wakelam, V.
Source :
Monthly Notices of the Royal Astronomical Society; Jan2015, Vol. 447 Issue 4, p4004-4017, 14p
Publication Year :
2015

Abstract

Recent observations have revealed the existence of complex organic molecules (COMs) in cold dense cores and pre-stellar cores. The presence of these molecules in such cold conditions is not well understood and remains a matter of debate since the previously proposed ‘warm-up’ scenario cannot explain these observations. In this paper, we study the effect of Eley–Rideal and complex induced reaction mechanisms of gas-phase carbon atoms with the main ice components of dust grains on the formation of COMs in cold and dense regions. Based on recent experiments, we use a low value for the chemical desorption efficiency (which was previously invoked to explain the observed COM abundances). We show that our introduced mechanisms are efficient enough to produce a large amount of COMs in the gas phase at temperatures as low as 10 K. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00358711
Volume :
447
Issue :
4
Database :
Complementary Index
Journal :
Monthly Notices of the Royal Astronomical Society
Publication Type :
Academic Journal
Accession number :
101039013
Full Text :
https://doi.org/10.1093/mnras/stu2709