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Click chemistry mediated synthesis of bio-inspired phosphonyl-functionalized ionic liquids.

Authors :
Braun, Richard A.
Bradfield, Joseph L.
Mobarrez, Niloufar
Sheng, Yinghong
Mirjafari, Arsalan
Henderson, Codey B.
O'Brien, Richard A.
Stenson, Alexandra C.
Davis, James H.
Source :
Green Chemistry; 2015, Vol. 17 Issue 2, p1259-1268, 10p
Publication Year :
2015

Abstract

This study focuses on the synthesis of a class of novel biologically-inspired ionic liquids coupled with a phosphonate group containing short to long side chains (C<subscript>3</subscript>–C<subscript>11</subscript>) via the Pudovic reaction. The ionic liquids exhibited very low glass transition temperatures and were hydrophobic in character. This method has the attributes of “click” chemistry with outstanding efficiency, simplicity, yields and regioselectivity. The results of their calcium(ii) ligating capability are also presented. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14639262
Volume :
17
Issue :
2
Database :
Complementary Index
Journal :
Green Chemistry
Publication Type :
Academic Journal
Accession number :
100937987
Full Text :
https://doi.org/10.1039/c4gc01933d